LEDs Magazine
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Semiconductors are very similar to insulators. The two categories of solids differ primarily in that insulators have larger band gaps — energies that electrons must acquire to be free to flow. In semiconductors at room temperature, just as in insulators, very few electrons gain enough thermal energy to leap the band gap, which is necessary for conduction. For this reason, pure semiconductors and insulators, in the absence of applied fields, have roughly similar electrical properties. The smaller bandgaps of semiconductors, however, allow for many other means besides temperature to control their electrical properties.

